If I was injured by company truck driven by my boss, am I able to sue his car insurer after I am done with workmans comp?

Question Details:

I was hit by my boss while he was driving a company truckwhile on the job. I have since filed for workmans' comp and gotten a lawyer. This was all 2months ago. From what I understand, he is lying and telling the workmans' comp company that I am lying. Therefore this has all been long and dragged out, and eventually will go to court. After all the workmans' comp settlement stuff is out of the way, can I go after his car insurance company as well, since he hit me due to negligence?

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