I am a CA lawyer. For an answer to your question, look at CA Vehicle Code section 17151, which states that the owner of the vehicle is liable up to $15,000. (Since you cannot "stack" policies, since there is insurance, there should be no exposure.) Like many laws, there is an exception to the $15,000 limit. If the plaintiff can prove negligent entrustment in letting your brother use car, there is no $15,000 limitation (if your brother was an owner, then negligent entrustment may not apply). I recommend you contact the insurance company and make sure they are protecting your family pursuant to the insurance contract. Sorry about your loss.